A Structural Study on Indium Tris-thiocarbamates

نویسندگان

  • S. Bhattacharya
  • Neena Seth
  • V. D. Gupta
  • H. Nöth
  • M. Thomann
چکیده

Indium Tris-thiocarbamates, *H N M R Spectra Indium tris(thiocarbamates) In(S2CN'Pr2)3 (1), In(SOCN'Pr2)3 (2) and In(S2CNC4H4)3 (3) have been synthesized and characterized. Variable temperature *H NM R spectra of 1 and 2 are reported. The X-ray molecular structures of 1 and 3 are found to be quite similar; the symmetry of the In(S2C)3 unit in 3 is close to point group D 3 with small asymmetry in the In -S bonds.

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تاریخ انتشار 2013